Battery

ABSTRACT

A battery includes a first positive electrode collector, a first negative electrode collector, a first power generating element, a second power generating element, and a first insulating part. The first and second power generating elements each include a positive electrode active material-containing layer, a negative electrode active material-containing layer, and an inorganic solid electrolyte-containing layer. In each of the first and second power generating elements, the inorganic solid electrolyte layer is in contact with the positive electrode active material-containing layer and the negative electrode active material-containing layer. The positive electrode active material layers of the first and second power generating elements are in contact with the first positive electrode collector. The negative electrode active material layers of the first and second power generating elements are in indirect contact with the first negative electrode collector. The first insulating part is disposed between the first and second power generating elements.

This is a continuation application of U.S. patent application Ser. No.15/073,597, filed Mar. 17, 2016, which claims priority to JapanesePatent Application No. 2015-171628, filed Sep. 1, 2015 and JapanesePatent Application No. 2015-090147, filed Apr. 27, 2015. The disclosuresof these documents, including the specifications, drawings, and claims,are incorporated herein by reference in their entirety.

BACKGROUND 1. Technical Field

The present disclosure relates to a battery.

2. Description of the Related Art

Japanese Unexamined Patent Application Publication No. 2002-216846discloses a sheet battery composed of a plurality of internal electrodeassemblies electrically connected to one another through currentcollector connecting portions.

SUMMARY

One non-limiting and exemplary embodiment provides a battery having highreliability, which has been demanded in known techniques.

In one general aspect, the techniques disclosed here feature a batteryincluding a first positive electrode collector, a first negativeelectrode collector, a first power generating element, a second powergenerating element, and a first insulating part. The first powergenerating element and the second power generating element each includea positive electrode active material layer containing a positiveelectrode active material, a negative electrode active material layercontaining a negative electrode active material, and an inorganic solidelectrolyte layer containing an inorganic solid electrolyte. In each ofthe first power generating element and the second power generatingelement, the inorganic solid electrolyte layer is in contact with boththe positive electrode active material layer and the negative electrodeactive material layer. The positive electrode active material layer ofthe first power generating element and the positive electrode activematerial layer of the second power generating element are in contactwith the first positive electrode collector. The negative electrodeactive material layer of the first power generating element and thenegative electrode active material layer of the second power generatingelement are in contact with the first negative electrode collector. Thefirst insulating part is disposed between the first power generatingelement and the second power generating element.

The present disclosure can achieve a battery having high reliability.

Additional benefits and advantages of the disclosed embodiments willbecome apparent from the specification and drawings. The benefits and/or

advantages may be individually obtained by the various embodiments andfeatures of the specification and drawings, which need not all beprovided in order to obtain one or more of such benefits and/oradvantages.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a diagram illustrating the schematic configuration of abattery according to Embodiment 1;

FIG. 2 includes diagrams illustrating the schematic configurations ofthe top surface and the side surface of the battery according toEmbodiment 1;

FIG. 3 is a diagram illustrating the schematic configuration of amodification example, battery, according to Embodiment 1;

FIG. 4 is a diagram illustrating the schematic configuration of anothermodification example, battery, according to Embodiment 1;

FIG. 5 is a diagram illustrating the schematic configuration of anothermodification example, battery, according to Embodiment 1;

FIG. 6 includes diagrams illustrating the schematic configurations ofthe top surface and the side surface of another modification example,battery, according to Embodiment 1;

FIG. 7 is a diagram explaining a method for producing a batteryaccording to Embodiment 1;

FIG. 8 is a diagram illustrating the schematic configuration of abattery according to Embodiment 2;

FIG. 9 is a diagram illustrating occurrence of a damage in a powergenerating element of the battery according to Embodiment 2;

FIG. 10 is a diagram illustrating the schematic configuration of acomparative example, battery;

FIG. 11 is a diagram illustrating occurrence of a damage in a powergenerating element of the comparative example, battery;

FIG. 12 is a diagram illustrating a method for producing a batteryaccording to Embodiment 2;

FIG. 13 is a diagram illustrating the schematic configuration of abattery according to Embodiment 3;

FIG. 14 is a diagram illustrating the schematic configuration of amodification example, battery, according to Embodiment 3;

FIG. 15 is a diagram illustrating the schematic configuration of abattery according to Embodiment 4;

FIG. 16 is a diagram illustrating the schematic configuration of amodification example, battery, according to Embodiment 4;

FIG. 17 is a diagram illustrating the schematic configuration of abattery according to Embodiment 5; and

FIG. 18 is a diagram illustrating the schematic configuration of abattery including four layers stacked in a bipolar arrangement.

DETAILED DESCRIPTION

The Embodiments will now be described with reference to the drawings.

Embodiment 1

FIG. 1 is a diagram (cross-sectional view) illustrating the schematicconfiguration of a battery 1000 according to Embodiment 1.

The battery 1000 in Embodiment 1 includes a first positive electrodecollector PC1, a first negative electrode collector NC1, a first powergenerating element U1, a second power generating element U2, and a firstinsulating part 101.

The first power generating element U1 includes a positive electrodeactive material layer PA1, a negative electrode active material layerNA1, and an inorganic solid electrolyte layer SE1.

In the first power generating element U1, the inorganic solidelectrolyte layer SE1 is in contact with the positive electrode activematerial layer PA1 and the negative electrode active material layer NA1.

The second power generating element U2 includes a positive electrodeactive material layer PA2, a negative electrode active material layerNA2, and an inorganic solid electrolyte layer SE2.

In the second power generating element U2, the inorganic solidelectrolyte layer SE2 is in contact with the positive electrode activematerial layer PA2 and the negative electrode active material layer NA2.

The positive electrode active material layer PA1 of the first powergenerating element U1 and the positive electrode active material layerPA2 of the second power generating element U2 are in contact with thefirst positive electrode collector PC1.

The negative electrode active material layer NA1 of the first powergenerating element U1 and the negative electrode active material layerNA2 of the second power generating element U2 are in contact with thefirst negative electrode collector NC1.

The first insulating part 101 is disposed between the first powergenerating element U1 and the second power generating element U2.

The configuration described above can prevent the influence of a damageoccurred in one power generating element from propagating to anotherpower generating element.

For example, if a shock or vibration applied to a battery causes adamage (e.g., cracking or breakage) in a part of the power generatingelements, the first insulating part functions as a partition wall. Thatis, the first insulating part prevents the damage from penetrating tothe adjacent power generating element. As a result, the expansion of thedamaged portion can be prevented, and undamaged power generatingelements normally function, for example, even if the damaged powergenerating element loses its function of generating power. Consequently,the battery can maintain the power generating function.

In addition, since the member containing the inorganic solid electrolyteis highly brittle, cracking or breakage readily occurs in the membercontaining the inorganic solid electrolyte. Accordingly, in theconfiguration of Embodiment 1, adjacent power generating elements arephysically separated from each other with the first insulating part.Consequently, the material (e.g., active material powder) exfoliatedfrom the damaged power generating element is prevented from coming intocontact with the adjacent undamaged power generating element. That is,the adjacent power generating element can be prevented from a shortcircuit due to adhesion of the exfoliated material.

A battery is probably damaged when the battery is dropped during themanufacturing, transporting, or use thereof or is probably damaged bythe vibration or shock involved in handling of the battery or the stressor deformation due to expansion and contraction of the active materialsof the battery by the charge and discharge. In the damaged portion, forexample, the internal resistance is significantly increased to block theflow of ions or electrons. As a result, the characteristics of thebattery decrease. If the damage is terrific, the power generatingfunction of the battery may be lost.

Against such damages, the configuration of Embodiment 1 can prevent thecharacteristics of the battery from being decreased and the powergenerating function from being lost, even if a part of the powergenerating elements is damaged. Consequently, a battery having a longservice life and high reliability can be achieved.

FIG. 2 includes diagrams illustrating the schematic configurations ofthe top and side surfaces of the battery 1000 according to Embodiment 1.

In the example shown in FIG. 2, the first insulating part 101 isdisposed along the y-direction.

The first insulating part 101 may be disposed in an oblique direction soas to extend also in the x-direction on the xy-plane.

As shown in FIGS. 1 and 2, the first insulating part 101 may be disposedsuch that the gap between the first power generating element U1 and thesecond power generating element U2 is densely filled with the firstinsulating part 101.

FIG. 3 is a diagram illustrating the schematic configuration of amodification example, battery 1100, according to Embodiment 1.

As in the battery 1100 shown in FIG. 3, a first void 21 may be disposedbetween the first insulating part 101 and the first power generatingelement U1.

In addition, as in the battery 1100 shown in FIG. 3, a second void 22may be disposed between the first insulating part 101 and the secondpower generating element U2.

Alternatively, in the configuration of Embodiment 1, only one of thefirst void 21 and the second void 22 may be disposed.

FIG. 4 is a diagram illustrating the schematic configuration of anothermodification example, battery 1200, according to Embodiment 1.

As in the battery 1200 shown in FIG. 4, the first insulating part 101may be disposed so as to cover the negative electrode active materiallayer NA1 and the negative electrode active material layer NA2 and notto cover the positive electrode active material layer PA1 and thepositive electrode active material layer PA2. In such a case, a void 23may be disposed.

FIG. 5 is a diagram illustrating the schematic configuration of anothermodification example, battery 1300, according to Embodiment 1.

As in the battery 1300 shown in FIG. 5, the first insulating part 101may be disposed so as to cover the positive electrode active materiallayer PA1 and the positive electrode active material layer PA2 and notto cover the negative electrode active material layer NA1 and thenegative electrode active material layer NA2. In such a case, a void 24may be disposed.

As shown in FIGS. 1 to 5, the first insulating part 101 may be disposedin any manner such that the positive electrode active material layer ofone power generating element and the negative electrode active materiallayer of adjacent another power generating element are physicallyseparated from each other with the first insulating part 101.

FIG. 6 includes diagrams illustrating the schematic configurations ofthe top and side surfaces of the battery 1400 according to Embodiment 1.

As shown in FIG. 6, the battery 1400 may include power generatingelements Ua, Ub, Uc, Ud, Ue, and Uf.

In addition, as shown in FIG. 6, the battery 1400 may include insulatingparts 101 a, 101 b, and 101 c each disposed between a pair of adjacentpower generating elements.

In Embodiment 1, the number of the power generating elements may be twoor more.

In Embodiment 1, the positions and the directions of the insulatingparts may be uniformly arranged in the vertical direction (y-direction)or the horizontal direction (x-direction) with respect to the faces ofthe power generating elements. Such a configuration makes themanufacturing easy.

In an all-solid-state lithium secondary battery for a portableelectronic device, such as a smartphone or a digital camera, the totalarea of the principal surfaces of the power generating elements may be 1to 100 cm².

Alternatively, in an all-solid-state lithium secondary battery as apower source for a large mobile apparatus, such as an electric vehicle,the total area of the principal surfaces of the power generatingelements may be 100 to 1000 cm².

The inorganic solid electrolyte layer contains an inorganic solidelectrolyte.

Usable examples of the inorganic solid electrolyte include oxide solidelectrolytes and sulfide solid electrolytes.

Usable examples of the oxide solid electrolyte include NASICON solidelectrolytes represented by LiTi₂(PO₄)₃ and element substituted productsthereof; (LaLi)TiO₃-based perovskite solid electrolytes; LISICON solidelectrolytes represented by Li₁₄ZnGe₄O₁₆, Li₄SiO₄, and LiGeO₄ andelement substituted products thereof; garnet solid electrolytesrepresented by Li₇La₃Zr₂O₁₂ and element substituted products thereof;Li₃N and H-substituted products thereof; and Li₃PO₄ and N-substitutedproducts thereof.

Usable examples of the sulfide solid electrolyte include Li₂S—P₂S₅,Li₂S—SiS₂, Li₂S—B₂S₃, Li₂S—GeS₂, Li_(3.25)Ge_(0.25)P_(0.75)S₄, andLi₁₀GeP₂S₁₂. These electrolytes may be mixed with, for example, LiX (X:F, Cl, Br, or I), MO_(y), or Li_(x)MO_(y) (M: P, Si, Ge, B, Al, Ga, orIn) (x, y: each natural number). Li₂S—P₂S₅ has a high ionic conductivityand is hardly reduced at a low potential. The use of Li₂S—P₂S₅ thereforemakes the construction of a battery easy.

The inorganic solid electrolyte may have a thickness of 1 to 100 μm. Athickness of the inorganic solid electrolyte of less than 1 μm increasesthe risk of causing a short circuit between the positive electrodeactive material layer and the negative electrode active material layer.A thickness of the inorganic solid electrolyte of larger than 100 μm maymake a high output operation difficult.

The positive electrode active material layer contains a positiveelectrode active material. The positive electrode active material layermay be a positive electrode mixture layer containing a positiveelectrode active material and an inorganic solid electrolyte. Thepositive electrode active material layer may contain a conductiveassistant for reducing the electrode resistance. The positive electrodeactive material layer may contain a binding agent for improving thebinding ability between positive electrode active material particles orthe binding ability between the positive electrode mixture layer and acurrent collector.

The positive electrode mixture layer may have a thickness of 10 to 500μm. A thickness of the positive electrode mixture layer of less than 10μm may make the achievement of a sufficient energy density of thebattery difficult. A thickness of the positive electrode mixture layerof larger than 500 μm may make a high output operation difficult.

The positive electrode active material may be, for example, a materialthat occludes and releases metal ions. The positive electrode activematerial may be, for example, a material that occludes and releaselithium ions. Usable examples of the positive electrode active materialinclude lithium-containing transition metal oxides, transition-metalfluorides, polyanion and fluorinated polyanion materials, andtransition-metal sulfides. Use of a lithium ion-containing transitionmetal oxide can reduce the manufacturing cost and increase the averagedischarge voltage.

The negative electrode active material layer contains a negativeelectrode active material. The negative electrode active material layermay be a negative electrode mixture layer containing a negativeelectrode active material and an inorganic solid electrolyte. Thenegative electrode active material layer may contain a conductiveassistant for reducing the electrode resistance. The negative electrodeactive material layer may contain a binding agent for improving thebinding ability between negative electrode active material particles orthe binding ability between the negative electrode mixture layer and acurrent collector.

The negative electrode mixture layer may have a thickness of 10 to 500μm. A thickness of the negative electrode mixture layer of less than 10μm may make the achievement of a sufficient energy density of thebattery difficult. A thickness of the negative electrode mixture layerof larger than 500 μm may make a high output operation difficult.

The negative electrode mixture layer may have a thickness larger thanthat of the positive electrode mixture layer. Such a configuration canreduce the load applied to the negative electrode to prolong the servicelife of the battery.

The negative electrode active material may be, for example, a materialthat occludes and releases metal ions. The negative electrode activematerial may be, for example, a material that occludes and releaselithium ions. Usable examples of the negative electrode active materialinclude lithium metal, metals or alloys alloying with lithium, carbonmaterials, transition metal oxides, and transition metal sulfides.Usable examples of the carbon material include graphite and non-graphitecarbon materials, such as hard carbon and coke. Usable examples of thetransition metal oxide include CuO and NiO. Usable examples of thetransition metal sulfide include copper sulfide denoted by CuS. Usableexamples of the metal or alloy alloying with lithium include siliconcompounds, tin compounds, and alloys of aluminum compounds and lithium.Use of the carbon material can reduce the manufacturing cost andincrease the average discharge voltage.

Usable examples of the conductive assistant include graphites, such asnatural graphite and artificial graphite; carbon blacks, such asacetylene black and Ketjen black; conductive fibers, such as carbonfibers and metal fibers; carbon fluoride; metal powders, such asaluminum powders; conductive whiskers, such as zinc oxide and potassiumtitanate; conductive metal oxides, such as titanium oxide; andconductive polymers, such as polyanion, polypyrrole, and polythiophene.Use of the carbon conductive assistant can reduce the cost.

Usable examples of the binding agent include polyvinylidene fluoride,polytetrafluoroethylene, polyethylene, polyacrylonitrile,hexafluoropolypropylene, styrene-butadiene rubber, and carboxymethylcellulose.

Usable examples of the positive electrode collector include porous ornon-porous sheets or films made of metal materials, such as aluminum,stainless steel, titanium, and alloys thereof. Aluminum and alloysthereof are inexpensive and can be readily formed into thin films. Thesheets or films may be, for example, metal foil or mesh.

The positive electrode collector may have a thickness of 1 to 30 μm. Athickness of the positive electrode collector of less than 1 μm isinsufficient in mechanical strength and readily causes cracking orbreakage in the current collector. A thickness of the positive electrodecollector of larger than 30 μm has a risk of reducing the energy densityof the battery.

Usable examples of the negative electrode collector include porous ornon-porous sheets or films made of metal materials, such as stainlesssteel, nickel, copper, and alloys thereof. Copper and alloys thereof areinexpensive and can be readily formed into thin films. The sheets orfilms may be, for example, metal foil or mesh.

The negative electrode collector may have a thickness of 1 to 30 μm. Athickness of the negative electrode collector of less than 1 μm isinsufficient in mechanical strength and readily causes cracking orbreakage in the current collector. A thickness of the negative electrodecollector of larger than 30 μm has a risk of reducing the energy densityof the battery.

The insulating part may be, for example, a member containing aninsulating material.

The insulating material may be, for example, an inorganic insulatingmaterial. Usable examples of the inorganic insulating material includesimple oxides, such as SiO₂, MgO, Al₂O₃, and ZrO₂; complex oxidescontaining two or more simple oxides; metal nitrides, such as AlN andSi₃N₄; and metal carbides, such as SiC.

Alternatively, the insulating material may be, for example, an organicinsulating material. Usable examples of the organic insulating materialinclude organic polymers, such as polyvinylidene fluoride,polytetrafluoroethylene, polyethylene, polypropylene, aramid resin,polyamide, polyimide, polyamidoimide, polyacrylonitrile, polyacrylicacid, polyacrylic acid methyl ester, polyacrylic acid ethyl ester,polyacrylic acid hexyl ester, polymethacrylic acid, polymethacrylic acidmethyl ester, polymethacrylic acid ethyl ester, polymethacrylic acidhexyl ester, polyvinyl acetate, polyvinylpyrrolidone, polyether,polyether sulfone, hexafluoropolypropylene, and carboxymethyl cellulose.Alternatively, the organic insulating material may be rubber, such assilicone rubber, chloroprene rubber, nitrile butadiene rubber, ethylenepropylene rubber, chlorosulfonated polyethylene rubber, acrylic rubber,urethane rubber, fluororubber, polysulfide rubber, natural rubber,isoprene rubber, styrene-butadiene rubber, butyl rubber, and butadienerubber.

The insulating part may have a width (thickness in the x-direction) of 1to 10000 μm. A width of the insulating part of less than 1 μm maycomplicate the manufacturing thereof, whereas a width of the insulatingpart of larger than 10000 μm may reduce the energy density of thebattery.

The insulating part may have a Young's modulus of 20 GPa or less. Thepositive electrode mixture layer, inorganic solid electrolyte layer, andnegative electrode mixture layer constituting a power generating elementeach have a Young's modulus of larger than about 20 GPa. Accordingly,the insulating part having a Young's modulus less than those of theselayers and disposed between adjacent power generating elements canbetter function as a partition wall that prevents the damage occurred ina part of the power generating elements from penetrating to the adjacentpower generating element. That is, stress or deformation occurred in apower generating element can be relieved by the insulating part having alow Young's modulus.

Method of Production

An example of a method for producing a battery according to Embodiment 1will now be described.

FIG. 7 is a diagram explaining a method for producing a batteryaccording to Embodiment 1.

The method for producing a battery according to Embodiment 1 includessteps A1, A2, A3, A4, and A5.

In step A1, a paste (insulating part 101) prepared by adding a solventto an insulating material is applied onto a negative electrode collectorNC.

In step A2, which is performed after step 1, a paste prepared by addinga solvent to a negative electrode active material is applied onto thenegative electrode collector NC in a strip form with a slit dieaccording to the width of the applied insulating material to form anegative electrode active material layer NA.

In step A3, which is performed after step A2, a paste prepared by addinga solvent to an inorganic solid electrolyte is applied onto the negativeelectrode active material layer NA in a strip form to form an inorganicsolid electrolyte layer SE. The width of each strip is adjusted to thatof the underlying negative electrode active material layer NA.

In step A4, which is performed after step A3, a paste prepared by addinga solvent to a positive electrode active material is applied onto theinorganic solid electrolyte layer SE in a strip form to form a positiveelectrode active material layer PA. The width of each strip is adjustedto that of the underlying inorganic solid electrolyte layer SE.

In step A5, which is performed after step A4, a positive electrodecollector PC is pressure-bonded to the positive electrode activematerial layer PA.

As described above, the insulating material may be applied onto thenegative electrode collector. Alternatively, the stacking order may bereversed. That is, an insulating material is applied onto a positiveelectrode collector, and a positive electrode active material layer, aninorganic solid electrolyte layer, a negative electrode active materiallayer, and a negative electrode collector may be then stacked in thisorder.

The width or the height of the insulating material to be applied in stepA1 and the width of the slit die used in each of steps A2 to A4 may beappropriately changed or determined according to the form anddisposition of the insulating material.

The positive electrode collector PC may be provided with a positiveelectrode terminal. The negative electrode collector NC may be providedwith a negative electrode terminal.

Embodiment 2

Embodiment 2 will now be described, but the explanation duplicated withEmbodiment 1 is appropriately omitted.

FIG. 8 is a diagram illustrating the schematic configuration of abattery 2000 according to Embodiment 2.

The battery 2000 in Embodiment 2 has a configuration including aplurality of power generating devices, having the same configuration asthat in the battery 1000 of Embodiment 1, stacked in a bipolararrangement.

The number of the stacked power generating devices can be appropriatelydetermined according to the use of the battery. FIG. 8 shows a stack oftwo layers, as an example.

The battery 2000 according to Embodiment 2 includes a first positiveelectrode collector PC1, a second positive electrode collector PC2, afirst negative electrode collector NC1, a second negative electrodecollector NC2, a first power generating element U1, a second powergenerating element U2, a third power generating element U3, a fourthpower generating element U4, a first insulating part 101, and a secondinsulating part 102.

The first power generating element U1 includes a positive electrodeactive material layer PA1, a negative electrode active material layerNA1, and an inorganic solid electrolyte layer SE1.

In the first power generating element U1, the inorganic solidelectrolyte layer SE1 is in contact with the positive electrode activematerial layer PA1 and the negative electrode active material layer NA1.

The second power generating element U2 includes a positive electrodeactive material layer PA2, a negative electrode active material layerNA2, and an inorganic solid electrolyte layer SE2.

In the second power generating element U2, the inorganic solidelectrolyte layer SE2 is in contact with the positive electrode activematerial layer PA2 and the negative electrode active material layer NA2.

The third power generating element U3 includes a positive electrodeactive material layer PA3, a negative electrode active material layerNA3, and an inorganic solid electrolyte layer SE3.

In the third power generating element U3, the inorganic solidelectrolyte layer SE3 is in contact with the positive electrode activematerial layer PA3 and the negative electrode active material layer NA3.

The fourth power generating element U4 includes a positive electrodeactive material layer PA4, a negative electrode active material layerNA4, and an inorganic solid electrolyte layer SE4.

In the fourth power generating element U4, the inorganic solidelectrolyte layer SE4 is in contact with the positive electrode activematerial layer PA4 and the negative electrode active material layer NA4.

The positive electrode active material layer PA1 of the first powergenerating element U1 and the positive electrode active material layerPA2 of the second power generating element U2 are in contact with thefirst positive electrode collector PC1.

The negative electrode active material layer NA1 of the first powergenerating element U1 and the negative electrode active material layerNA2 of the second power generating element U2 are in contact with thefirst negative electrode collector NC1.

The positive electrode active material layer PA3 of the third powergenerating element U3 and the positive electrode active material layerPA4 of the fourth power generating element U4 are in contact with thesecond positive electrode collector PC2.

The negative electrode active material layer NA3 of the third powergenerating element U3 and the negative electrode active material layerNA4 of the fourth power generating element U4 are in contact with thesecond negative electrode collector NC2.

The first negative electrode collector NC1 and the second positiveelectrode collector PC2 are in contact with each other.

The first insulating part 101 is disposed between the first powergenerating element U1 and the second power generating element U2.

The second insulating part 102 is disposed between the third powergenerating element U3 and the fourth power generating element U4.

In the configuration described above, even if a damage occurs in onepower generating element, other power generating elements can maintainthe power generating function. Consequently, the reduction in thecharacteristics of a battery and the loss of the power generatingfunction can be prevented, even if a part of the power generatingelements is damaged. As a result, a battery having a long service lifeand high reliability can be achieved.

The details of the advantageous effects will now be described withreference to a comparative example.

FIG. 9 is a diagram illustrating occurrence of a damage in a powergenerating element of the battery 2000 according to Embodiment 2.

In the example shown in FIG. 9, the first power generating element U1has a damage. In the first power generating element U1, therefore, theflow of ions or electric current is blocked.

In the battery 2000 of Embodiment 2, the third power generating elementU3 is electrically connected to the second power generating element U2through the first negative electrode collector NC1 and the secondpositive electrode collector PC2.

Therefore, as shown in FIG. 9, even if a damage occurred in the firstpower generating element U1, the power generating element of the thirdpower generating element U3 connected in series with the first powergenerating element U1 does not lose its power generating function.

Similarly, even if a damage occurred in any of the second powergenerating element U2, the third power generating element U3, and thefourth power generating element U4, other power generating elements canmaintain their power generating function.

FIG. 10 is a diagram illustrating the schematic configuration of acomparative example, battery 2100.

The comparative example battery 2100 includes a third positive electrodecollector PC3, a third negative electrode collector NC3, and aninsulating part 201.

Unlike the battery 2000 of Embodiment 2, in the comparative examplebattery 2100, the negative electrode active material layer NA2 of thesecond power generating element U2 is not in contact with the firstnegative electrode collector NC1.

In the comparative example battery 2100, the negative electrode activematerial layer NA2 of the second power generating element U2 is incontact with the third negative electrode collector NC3.

Unlike the battery 2000 of Embodiment 2, in the comparative examplebattery 2100, the positive electrode active material layer PA4 of thefourth power generating element U4 is not in contact with the secondpositive electrode collector PC2.

In the comparative example battery 2100, the positive electrode activematerial layer PA4 of the fourth power generating element U4 is incontact with the third positive electrode collector PC3.

The third positive electrode collector PC3 and the third negativeelectrode collector NC3 are in contact with each other.

The insulating part 201 is disposed so as to be between the thirdpositive electrode collector PC3 and the third negative electrodecollector NC3 and between the first negative electrode collector NC1 andthe second positive electrode collector PC2.

The third positive electrode collector PC3 is therefore not in contactwith the first negative electrode collector NC1 and the second positiveelectrode collector PC2.

Similarly, the third negative electrode collector NC3 is not in contactwith the first negative electrode collector NC1 and the second positiveelectrode collector PC2.

FIG. 11 is a diagram illustrating occurrence of a damage in a powergenerating element of the comparative example, battery 2100.

In the example shown in FIG. 11, the first power generating element U1has a damage. In the first power generating element U1, therefore, theflow of ions or electric current is blocked.

In the comparative example battery 2100, the third power generatingelement U3 is not electrically connected to the second power generatingelement U2.

Therefore, as shown in FIG. 11, when a damage occurred in the firstpower generating element U1, the power generating element of the thirdpower generating element U3 connected in series with the first powergenerating element U1 loses its power generating function.

As described above, unlike the comparative example, in the configurationof Embodiment 2, even if a damage occurred in one power generatingelement, the power generating function of other power generatingelements can be maintained.

A bipolar stacked all-solid-state lithium secondary battery may beformed by the battery 2000 of Embodiment 2.

The term “bipolar stacked” refers to a configuration including a bipolarelectrode as a component and two or more power generating elementsconnected in series.

The bipolar electrode has a positive electrode active material layer onone surface of a current collector and a negative electrode activematerial layer on the other side of the current collector.

The current collector used in the bipolar electrode may be common to thepositive electrode and the negative electrode or may be different in thepositive electrode and the negative electrode.

The bipolar stacked all-solid-state lithium secondary battery includes aplurality of power generating elements connected in series in a singleouter package and thereby can increase the volume energy densitycompared to ordinary all-solid-state lithium secondary batteries eachincluding a single power generating element in an outer package.

The stacked power generating devices may differ from one another in theconfiguration (for example, the number of the power generating elementsand the position and direction of the insulating part).

Alternatively, the stacked power generating devices may have the sameconfigurations. In such a case, the manufacturing is easy, and themanufacturing cost can be reduced.

The number of the stacked power generating devices may be two, forexample, in an all-solid-state lithium secondary battery for asmall-size electronic apparatus, such as a digital camera.Alternatively, the number of the stacked power generating devices may bethree to four, for example, in an all-solid-state lithium secondarybattery as a power source for the system controller of an automobile.Furthermore, the number of the stacked power generating devices may be 4to 200 in an all-solid-state lithium secondary battery as a power sourcefor a large mobile apparatus, such as an electric vehicle.

Method of Production

An example of a method for producing a battery according to Embodiment 2will now be described.

FIG. 12 is a diagram illustrating a method for producing a batteryaccording to Embodiment 2.

The method for producing a battery according to Embodiment 2 includessteps B1, B2, B3, and B4.

Step B1 produces a plurality of power generating devices by the methodof production described in Embodiment 1. On this occasion, the areas ofthe power generating devices may be the same.

In step B2, which is performed after step B1, the first power generatingdevice is inserted into an outer case 30 such that the negativeelectrode collector NC of the first power generating device is incontact with the negative electrode terminal NE.

In step B3, which is performed after step B2, power generating devicesare sequentially stacked in the outer case 30 such that the negativeelectrode collector NC of the upper power generating device is incontact with the positive electrode collector PC of the lower powergenerating device.

In step B4, which is performed after step B3, the outer case 30 issealed with a lid 40 of the outer case 30 having a positive electrodeterminal PE such that the uppermost positive electrode collector PC isin contact with the positive electrode terminal PE.

As described above, the battery may be produced such that the negativeelectrode collector is disposed at the bottom. Alternatively, the orderof the stacking may be reversed. That is, the power generating devicesmay be sequentially stacked in an outer case provided with a positiveelectrode terminal PE in advance such that a positive electrodecollector PC is disposed at the bottom.

Embodiment 3

Embodiment 3 will now be described, but the explanation duplicated withEmbodiment 1 or 2 is appropriately omitted.

FIG. 13 is a diagram illustrating the schematic configuration of abattery 3000 according to Embodiment 3.

The battery according to Embodiment 3 further includes the followingconfiguration, in addition to the configuration shown in Embodiment 1.

That is, in the battery of Embodiment 3, at least one of the firstpositive electrode collector PC1 and the first negative electrodecollector NC1 includes a first continuity control layer T1 and a secondcontinuity control layer T2.

The electrical resistance of the first continuity control layer T1increases with the temperature increase. For example, the electricalresistance of the first continuity control layer T1 is increased by heatabnormally generated in the first power generating element U1.

The electrical resistance of the second continuity control layer T2increases with the temperature increase. For example, the electricalresistance of the second continuity control layer T2 is increased byheat abnormally generated in the second power generating element U2.

The first continuity control layer T1 is disposed on the side where thefirst power generating element U1 is located.

The second continuity control layer T2 is disposed on the side where thesecond power generating element U2 is located.

The configuration described above can achieve the following advantageouseffects.

For example, if a shock or vibration applied to the battery 1000according to Embodiment 1 damages a part of the power generatingelements and mixes the positive electrode mixture layer and the negativeelectrode mixture layer to cause an internal short-circuit, theresistance of the damaged power generating element is significantlydecreased by the internal short-circuit, and the electrical current isconcentrated. As a result, no electrical current flows in undamagedpower generating elements, and the voltage is thereby reduced.Consequently, the voltage of the battery may be reduced to a level lowerthan the voltage necessary for operating the device or system that isdriven by the battery. As a result, the operation of the device orsystem may stop.

In the battery according to Embodiment 3, however, the resistance of thecontinuity control layer disposed between the power generating elementand the current collector is significantly increased by the Joule heatgenerated by the concentration of a current caused by an internalshort-circuit in a part of the power generating elements. As a result,the flow of electrical current into the damaged power generating elementis blocked, and the current flows into undamaged power generatingelements. That is, although the voltage is temporarily decreased by theconcentration of a current in the damaged power generating element atimmediately after the internal short-circuit, the voltage recovers tothe initial level by the work of the continuity control layer.Consequently, even if a power generating element is damaged, the deviceor system driven by the battery is continuously operated.

In batteries connected in parallel, since the battery containing adamaged power generating element can be prevented from power generationfailure, the load is not concentrated in the battery connected inparallel to the battery containing the damaged power generating element.

The first continuity control layer T1 and the second continuity controllayer T2 may be constituted as, for example, positive temperaturecoefficient (PTC) devices. In such a case, the electrical resistances ofthe first continuity control layer T1 and the second continuity controllayer T2 are each increased at a prescribed temperature or more.

Alternatively, the first continuity control layer T1 and the secondcontinuity control layer T2 may be constituted as, for example, thermalfuses. In such a case, the continuity of a current is blocked in each ofthe first continuity control layer T1 and the second continuity controllayer T2 at a prescribed temperature or more (for example, thecontinuity control layer is partially molten at a prescribed temperatureor more and is thereby irreversibly insulated).

The first continuity control layer T1 and the second continuity controllayer T2 can have generally known configurations and can be made ofgenerally known materials. For example, the first continuity controllayer T1 and the second continuity control layer T2 can be each made bydispersing a conductive material (e.g., a metal or carbon) in a polymer(e.g., polypropylene or polyethylene).

In the battery 3000 shown in FIG. 13, the first positive electrodecollector PC1 includes a first continuity control layer T1 and a secondcontinuity control layer T2.

In the battery 3000 shown in FIG. 13, the first continuity control layerT1 is in contact with the first power generating element U1 (e.g., thepositive electrode active material layer PA1), and the second continuitycontrol layer T2 is in contact with the second power generating elementU2 (e.g., the positive electrode active material layer PA2).

FIG. 14 is a diagram illustrating the schematic configuration of amodification example, battery 3100, according to Embodiment 3.

In the battery 3100 shown in FIG. 14, the first negative electrodecollector NC1 includes a first continuity control layer T1 and a secondcontinuity control layer T2.

In the battery 3100 shown in FIG. 14, the first continuity control layerT1 is in contact with the first power generating element U1 (e.g., thenegative electrode active material layer NA1), and the second continuitycontrol layer T2 is in contact with the second power generating elementU2 (e.g., the negative electrode active material layer NA2).

In Embodiment 3, the first continuity control layer T1 and the secondcontinuity control layer T2 may be separated from each other with afirst insulating part 101.

That is, the first insulating part 101 may be disposed between the firstcontinuity control layer T1 and the second continuity control layer T2.

The configuration described above can prevent malfunction of the firstcontinuity control layer T1 or the second continuity control layer T2.That is, the first insulating part 101 can prevent the heat generated bya damage of the first power generating element U1 from penetrating tothe second continuity control layer T2. Consequently, the secondcontinuity control layer T2 can be prevented from malfunctioning due tothe heat generated by the damage of the first power generating elementU1. Similarly, the first insulating part 101 can prevent the heatgenerated by a damage of the second power generating element U2 frompenetrating to the first continuity control layer T1. Consequently, thefirst continuity control layer T1 can be prevented form malfunctioningdue to the heat generated by the damage of the second power generatingelement U2.

Method of Production

An example of a method for producing a battery according to Embodiment 3will now be described.

A method for producing a battery having the configuration shown in FIG.13 will now be described. This method for producing the batteryaccording to Embodiment 3 includes step X1 in addition to steps A1 to A5described in Embodiment 1.

In step X1, which is performed after step A4, a first continuity controllayer T1 and a second continuity control layer T2 are formed on apositive electrode active material layer PA. For example, the firstcontinuity control layer T1 and the second continuity control layer T2are applied in a strip form. The width of each strip is adjusted to thatof the underlying positive electrode active material layer PA.

In this case, in step A5, a positive electrode collector PC ispressure-bonded onto the first continuity control layer T1 and thesecond continuity control layer T2, after step X1.

A method for producing a battery having the configuration shown in FIG.14 will now be described. This method for producing the batteryaccording to Embodiment 3 includes step X2 in addition to steps A1 to A5described in Embodiment 1.

In step X2, which is performed after step A1, a first continuity controllayer T1 and a second continuity control layer T2 are formed on anegative electrode collector NC. For example, the first continuitycontrol layer T1 and the second continuity control layer T2 are formedin a strip form.

In this case, in step A2, which is performed after step X2, a negativeelectrode active material layer NA is formed on the first continuitycontrol layer T1 and the second continuity control layer T2.

As described above, the insulating material may be applied onto thenegative electrode collector. Alternatively, the order of the stackingmay be reversed. That is, an insulating material is applied onto apositive electrode collector, and a continuity control layer, a positiveelectrode active material layer, an inorganic solid electrolyte layer, anegative electrode active material layer, and a negative electrodecollector may be then stacked in this order. Alternatively, aninsulating material is applied onto a positive electrode collector, anda positive electrode active material layer, an inorganic solidelectrolyte layer, a negative electrode active material layer, acontinuity control layer, and a negative electrode collector may be thenstacked in this order.

Embodiment 4

Embodiment 4 will now be described, but the explanation duplicated withany of Embodiments 1 to 3 is appropriately omitted.

FIG. 15 is a diagram illustrating the schematic configuration of abattery 4000 according to Embodiment 4.

The battery in Embodiment 4 has a configuration including a plurality ofpower generating devices having the same configuration as that describedin Embodiment 3 and stacked in a bipolar arrangement.

The number of the stacked power generating devices can be appropriatelydetermined depending on the use of the battery. FIG. 15 shows a stack oftwo layers, as an example.

The battery in Embodiment 4 further includes the following configurationin addition to the configuration shown in Embodiment 3.

That is, the battery according to Embodiment 4 further includes a secondpositive electrode collector PC2, a second negative electrode collectorNC2, a third power generating element U3, a fourth power generatingelement U4, and a second insulating part 102.

The second positive electrode collector PC2, the second negativeelectrode collector NC2, the third power generating element U3, and thefourth power generating element U4 can be in the same configurations asthose shown in Embodiment 2.

In the battery of Embodiment 4, at least one of the second positiveelectrode collector PC2 and the second negative electrode collector NC2includes a third continuity control layer T3 and a fourth continuitycontrol layer T4.

The electrical resistance of the third continuity control layer T3increases with the temperature increase. For example, the electricalresistance of the third continuity control layer T3 is increased by heatabnormally generated in the third power generating element U3.

The electrical resistance of the fourth continuity control layer T4increases with the temperature increase. For example, the electricalresistance of the fourth continuity control layer T4 is increased byheat abnormally generated in the fourth power generating element U4.

The third continuity control layer T3 is disposed on the side where thethird power generating element U3 is located.

The fourth continuity control layer T4 is disposed on the side where thefourth power generating element U4 is located.

The configuration described above can achieve the following advantageouseffects.

In the battery according to Embodiment 4, if an internal short-circuitoccurs in a part of the power generating elements to cause concentrationof a current, the continuity control layer functions to allow thecurrent to flow into undamaged power generating elements. Although thevoltage is temporarily decreased by the concentration of a current inthe damaged power generating element at immediately after the internalshort-circuit, the voltage recovers to the initial level by the work ofthe continuity control layer. Consequently, even if a power generatingelement is damaged, the device or system driven by the battery iscontinuously operated.

In batteries connected in parallel, since the battery containing adamaged power generating element can be prevented from power generationfailure, the load is not concentrated in the battery connected inparallel to the battery containing the damaged power generating element.

The third continuity control layer T3 and the fourth continuity controllayer T4 can have the same configurations as those of the continuitycontrol layers shown in Embodiment 3 and can be made of the samematerials as those of the continuity control layers shown in Embodiment3.

In the battery 4000 shown in FIG. 15, the second positive electrodecollector PC2 includes a third continuity control layer T3 and a fourthcontinuity control layer T4.

In the battery 4000 shown in FIG. 15, the third continuity control layerT3 is in contact with the third power generating element U3 (e.g., thepositive electrode active material layer PA3), and the fourth continuitycontrol layer T4 is in contact with the fourth power generating elementU4 (e.g., the positive electrode active material layer PA4).

FIG. 16 is a diagram illustrating the schematic configuration of amodification example, battery 4100, according to Embodiment 4.

In the battery 4100 shown in FIG. 16, the second negative electrodecollector NC2 includes a third continuity control layer T3 and a fourthcontinuity control layer T4.

In the battery 4100 shown in FIG. 16, the third continuity control layerT3 is in contact with the third power generating element U3 (e.g., thenegative electrode active material layer NA3), and the fourth continuitycontrol layer T4 is in contact with the fourth power generating elementU4 (e.g., negative electrode active material layer NA4).

In Embodiment 4, the third continuity control layer T3 and the fourthcontinuity control layer T4 may be separated from each other with asecond insulating part 102.

That is, the second insulating part 102 may be disposed between thethird continuity control layer T3 and the fourth continuity controllayer T4.

The configuration described above can prevent malfunction of the thirdcontinuity control layer T3 or the fourth continuity control layer T4.That is, the second insulating part 102 can prevent the heat generatedby a damage of the third power generating element U3 from penetrating tothe fourth continuity control layer T4. Consequently, malfunction of thefourth continuity control layer T4 due to the heat generated by thedamage of the third power generating element U3 can be prevented.Similarly, the second insulating part 102 can prevent the heat generatedby a damage of the fourth power generating element U4 from penetratingto the third continuity control layer T3. Consequently, malfunction ofthe third continuity control layer T3 due to the heat generated by thedamage of the fourth power generating element U4 can be prevented.

Method of Production

An example of a method for producing a battery according to Embodiment 4will now be described.

A method for producing a battery having the configuration shown in FIG.15 will now be described. This method for producing the batteryaccording to Embodiment 4 includes step Y1 in addition to steps B2 to B4described in Embodiment 2.

Step Y1 produces a plurality of power generating devices by the methodincluding step X1 described in Embodiment 3. On this occasion, the areasof the power generating devices may be the same.

In this case, step B2 is performed after step Y1.

A method for producing a battery having the configuration shown in FIG.16 will now be described. This method for producing the batteryaccording to Embodiment 4 includes step Y2 in addition to steps B2 to B4described in Embodiment 2.

Step Y2 produces a plurality of power generating devices by the methodincluding step X2 described in Embodiment 3. On this occasion, the areasof the power generating devices may be the same.

In this case, step B2 is performed after step Y2.

As described above, the battery may be produced such that the negativeelectrode collector is disposed at the bottom. Alternatively, the orderof the stacking may be reversed. That is, the power generating devicesmay be sequentially stacked in an outer case provided with a positiveelectrode terminal PE in advance such that a positive electrodecollector PC is disposed at the bottom.

Embodiment 5

Embodiment 5 will now be described, but the explanation duplicated withany of Embodiments 1 to 4 is appropriately omitted.

FIG. 17 is a diagram illustrating the schematic configuration of abattery 5000 according to Embodiment 5.

The battery 5000 in Embodiment 5 further includes the followingconfiguration in addition to the configuration shown in Embodiment 4.

That is, the battery 5000 according to Embodiment 5 further includes afirst voltage detection terminal C1.

The first voltage detection terminal C1 is in contact with the firstnegative electrode collector NC1 or the second positive electrodecollector PC2.

The configuration described above can achieve the following advantageouseffects.

In the configuration of the battery shown in Embodiment 4, theoccurrence of an internal short-circuit can be detected based on thevoltage between the first positive electrode collector PC1 and thesecond negative electrode collector NC2, which is output as the batteryvoltage, but the place of the occurrence of internal short-circuitcannot be specified.

In the configuration of the battery according to Embodiment 5, theoccurrence of an internal short-circuit and also the layer having theinternal short-circuit can be detected by monitoring not only thebattery voltage but also the voltage between the first positiveelectrode collector PC1 and the first voltage detection terminal C1 orbetween the second negative electrode collector NC2 and the firstvoltage detection terminal C1 with a voltage detector.

The identification of the position of the internal short-circuit canverify the degree of the damage more precisely.

A method for installing voltage detectors will now be described in moredetail.

When the number of the layers stacked in a bipolar arrangement is n (n:natural number), the number of the voltage detectors is n−1.

The voltage detectors connect between adjacent voltage detectionterminals, between first positive electrode collector and the firstvoltage detection terminal, and between the n'th negative electrodecollector and the (n−1)'th voltage detection terminal. As a result, thelayer having an internal short-circuit can be identified.

FIG. 18 is a diagram illustrating the schematic configuration of abattery including four layers stacked in a bipolar arrangement.

The method for installing voltage detectors will be more specificallydescribed with reference to FIG. 18.

The layer including the power generating element being in contact withthe first positive electrode collector PC1 is defined as the firstlayer.

The layer including the power generating element being in contact withthe fourth negative electrode collector NC4 is defined as the fourthlayer.

A first voltage detector VC1 detecting the voltage between the firstpositive electrode collector PC1 and the first voltage detectionterminal C1 is installed.

A second voltage detector VC2 detecting the voltage between the firstvoltage detection terminal C1 and the second voltage detection terminalC2 is installed.

A third voltage detector VC3 detecting the voltage between the secondvoltage detection terminal C2 and the third voltage detection terminalC3 is installed.

A case of having occurrence of internal short-circuits in the first andfourth layers will now be described as an example.

The voltage per each layer is temporarily defined to be 4 V. On thisoccasion, the voltage decreases to about 0 V due to the internalshort-circuits in the first and fourth layers. The voltage then recoversto 4 V by the work of the continuity control layer.

At immediately after the occurrence of the internal short-circuits, thevoltage of the battery as a whole is 8 V, and the voltages detected bythe first voltage detector VC1, the second voltage detector VC2, and thethird voltage detector VC3 are respectively 0 V, 4 V, and 4 V.

The information on the voltage of the battery as a whole demonstratesthat the number of the layers having internal short-circuits is two.

The information from the first voltage detector VC1 demonstrates thatthe first layer has an internal short-circuit.

The information on the voltage of the battery as a whole and theinformation from the first voltage detector VC1, second voltage detectorVC2, and third voltage detector VC3 demonstrate that the fourth layerhas an internal short-circuit.

Thus, the layer having an internal short-circuit can be detected byinstalling (n−1) voltage detectors.

The battery of the present disclosure can be used as, for example, anall-solid-state lithium secondary battery.

While the present disclosure has been described with respect toexemplary embodiments thereof, it will be apparent to those skilled inthe art that the disclosure may be modified in numerous ways and mayassume many embodiments other than those specifically described above.Accordingly, it is intended by the appended claims to cover allmodifications of the disclosure that fall within the true spirit andscope of the disclosure.

What is claimed is:
 1. A battery comprising: a first positive electrodecollector; a first negative electrode collector; a first powergenerating element; a second power generating element; a firstinsulating part; a first continuity control layer in which an electricalresistance increases with temperature; a second continuity control layerin which an electrical resistance increases with temperature; a secondpositive electrode collector; a second negative electrode collector; athird power generating element; a fourth power generating element; and asecond insulating part, wherein the first power generating element andthe second power generating element each include a positive electrodeactive material layer containing a positive electrode active material, anegative electrode active material layer containing a negative electrodeactive material, and an inorganic solid electrolyte layer containing aninorganic solid electrolyte; the inorganic solid electrolyte layer inthe first power generating element is in contact with the positiveelectrode active material layer and the negative electrode activematerial layer in the first power generating element; the inorganicsolid electrolyte layer in the second power generating element is incontact with the positive electrode active material layer and thenegative electrode active material layer in the second power generatingelement; the positive electrode active material layer of the first powergenerating element and the positive electrode active material layer ofthe second power generating element are electrically connected with thefirst positive electrode collector; the negative electrode activematerial layer of the first power generating element and the negativeelectrode active material layer of the second power generating elementare electrically connected with the first negative electrode collector;the first insulating part is disposed between the first power generatingelement and the second power generating element; the third powergenerating element and the fourth power generating element each includea positive electrode active material layer containing a positiveelectrode active material, a negative electrode active material layercontaining a negative electrode active material, and an inorganic solidelectrolyte layer containing an inorganic solid electrolyte; theinorganic solid electrolyte layer in the third power generating elementis in contact with the positive electrode active material layer and thenegative electrode active material layer in the third power generatingelement; the inorganic solid electrolyte layer in the fourth powergenerating element is in contact with the positive electrode activematerial layer and the negative electrode active material layer in thefourth power generating element; the positive electrode active materiallayer of the third power generating element and the positive electrodeactive material layer of the fourth power generating element are incontact with the second positive electrode collector; the negativeelectrode active material layer of the third power generating elementand the negative electrode active material layer of the fourth powergenerating element are in contact with the second negative electrodecollector; the first negative electrode collector is in direct contactwith the second positive electrode collector; the second insulating partis disposed between the third power generating element and the fourthpower generating element, the first continuity control layer is betweenthe first negative electrode collector and the first power generatingelement or between the first positive electrode collector and the firstpower generating element; and the second continuity control layer isbetween the first negative electrode collector and the second powergenerating element or between the first positive electrode collector andthe second power generating element.
 2. The battery according to claim1, wherein the first insulating part has a width of 1 to 10000 μm. 3.The battery according to claim 1, wherein the first insulating part hasa Young's modulus of 20 GPa or less.
 4. The battery according to claim1, wherein the first continuity control layer and the second continuitycontrol layer are separated by the first insulating part.
 5. The batteryaccording to claim 1, further comprising: a third continuity controllayer in which an electrical resistance increases with temperature; anda fourth continuity control layer in which an electrical resistanceincreases with temperature, wherein the third continuity control layeris between the third power generating element and at least one of thesecond positive electrode collector and the second negative electrodecollector; and the fourth continuity control layer is between the fourthpower generating element and at least one of the second positiveelectrode collector and the second negative electrode collector.
 6. Thebattery according to claim 5, wherein the third continuity control layerand the fourth continuity control layer are separated by the secondinsulating part.
 7. The battery according to claim 5, furthercomprising: a voltage detection terminal, wherein the voltage detectionterminal is in contact with the first negative electrode collector orthe second positive electrode collector.